Change mySQL default character set for a specific user

Hello,
I want to change the default character set of mySQL for only one user. Is there any way to do it? I read here http://www.mysql.com/doc/en/Character_sets.html that

One can force the client to use specific character set by specifying:

[client]
default-character-set=character-set-name

Has anyone done this? Which file do I have to edit? What exactly do I have to add? Any help would be appreciated.

 

 

 

 

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